Breathe into the can before closing the lid:
I've seen this suggestion over and over. I suspect it works, but not my favorite. In theory, the "air" is replaced with carbon dioxide and it is less prone to skin.
Pour the size into smaller bottles or cans:
This is probably my favorite. You can buy lots of small bottles and fill each one to the top, you will only have small quantities of size to worry about at any particular time.

Check out http://www.ebottles.com
Pour the size into a squirt bottle, then store it upside down:
This one works fairly well as long as you make certain to get the lid snapped down well after use. The skin will form on the top of the size, which will be at the top of the upside down bottle.
Marbles in the can:
(Jeff Lang made this suggestion earlier on the forum). Go to K-Mart or Wal-Mart and buy a bag of cheap marbles. When you open a new can of gold size and use a little of it on a project, immediately drop in enough glass marbles to fill the size back up to the top and replace the lid. It keeps the amount of air in the can down to a minimum and keeps it from skinning over. I'm still on my first can of size, and it still seems to be working. Jeff says you can clean the old marbles with thinner when the can is used up and reuse the marbles on the next one.